Chemistry reference sheet
Made for regular and honors high school chemistry. Solubility rules differ a little between textbooks, so check yours.
Atoms and electrons
| Atomic number | number of protons (= electrons in a neutral atom) |
|---|---|
| Mass number | protons + neutrons |
| Average atomic mass | Σ (isotope mass × abundance as a decimal) |
| Filling order | 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d 7p |
| Sublevel capacity | s 2, p 6, d 10, f 14 |
| Periodic trends | radius gets smaller across a period and bigger down a group; ionization energy and electronegativity do the opposite |
| Diatomic elements | H2, N2, O2, F2, Cl2, Br2, I2 |
Common polyatomic ions
| +1 | NH4+ ammonium; H3O+ hydronium |
|---|---|
| −1 | OH− hydroxide; CN− cyanide; NO3− nitrate; NO2− nitrite; C2H3O2− acetate; MnO4− permanganate; SCN− thiocyanate; HCO3− hydrogen carbonate; HSO4− hydrogen sulfate; H2PO4− dihydrogen phosphate |
| Chlorine oxyanions (−1) | ClO− hypochlorite; ClO2− chlorite; ClO3− chlorate; ClO4− perchlorate |
| −2 | CO32− carbonate; SO42− sulfate; SO32− sulfite; S2O32− thiosulfate; CrO42− chromate; Cr2O72− dichromate; C2O42− oxalate; O22− peroxide; HPO42− hydrogen phosphate |
| −3 | PO43− phosphate |
| Name pattern | -ate has one more O than -ite; per-…-ate has one more O than -ate; hypo-…-ite has one fewer O than -ite |
Naming
| Ionic | cation, then anion (-ide for single atoms): NaCl sodium chloride |
|---|---|
| Transition metals | Roman numeral for the charge: FeCl3 iron(III) chloride |
| Covalent prefixes | mono, di, tri, tetra, penta, hexa, hepta, octa, nona, deca (no mono on the first element): N2O4 dinitrogen tetroxide |
| Acids | -ide → hydro-…-ic acid (HCl); -ate → -ic acid (HNO3 nitric); -ite → -ous acid (HNO2 nitrous) |
Solubility rules (common version)
| Always soluble | group 1 ions, NH4+, NO3−, acetate |
|---|---|
| Chlorides, bromides, iodides | soluble, except with Ag+, Pb2+, Hg22+ |
| Sulfates | soluble, except with Ba2+, Sr2+, Pb2+, Ca2+, Hg22+ |
| Carbonates, phosphates, sulfides | mostly insoluble, except with group 1 ions and NH4+ |
| Hydroxides | mostly insoluble, except group 1; Ca, Sr and Ba hydroxides are slightly soluble |
Reactions and moles
| Reaction types | synthesis A + B → AB; decomposition AB → A + B; single replacement A + BC → AC + B; double replacement AB + CD → AD + CB; combustion fuel + O2 → CO2 + H2O |
|---|---|
| Balancing | change coefficients, never subscripts |
| Moles | mol = grams ÷ molar mass; particles = mol × 6.022 × 1023; 1 mol of gas at STP = 22.4 L |
| Percent yield | actual ÷ theoretical × 100 |
| Percent by mass | mass of element ÷ mass of compound × 100 |
| Empirical formula | grams → moles, divide by the smallest, round to whole numbers |
Gas laws
| Boyle | P1V1 = P2V2 |
|---|---|
| Charles | V1/T1 = V2/T2 |
| Gay-Lussac | P1/T1 = P2/T2 |
| Avogadro | V1/n1 = V2/n2 |
| Combined | P1V1/T1 = P2V2/T2 (T in kelvin: K = °C + 273.15) |
| Ideal gas | PV = nRT; R = 0.0821 L·atm/(mol·K) = 8.314 L·kPa/(mol·K) |
| Dalton | Ptotal = P1 + P2 + … |
| Graham | rate1/rate2 = √(M2/M1) |
| Pressure units | 1 atm = 760 mm Hg = 760 torr = 101.325 kPa |
Solutions, heat and pH
| Molarity and molality | M = mol solute / L solution; m = mol solute / kg solvent |
|---|---|
| Dilution | M1V1 = M2V2 |
| Heat | q = mcΔT; melting q = mHf; boiling q = mHv |
| Water | c = 4.18 J/(g·°C); Hf = 334 J/g; Hv = 2260 J/g |
| pH | pH = −log[H+]; pOH = −log[OH−]; pH + pOH = 14 at 25 °C |
Measurement
| Percent error | |measured − accepted| ÷ accepted × 100 |
|---|---|
| Sig figs | nonzero digits count; zeros between them count; leading zeros never count; trailing zeros count only with a decimal point |
| Rounding | × and ÷ keep the fewest sig figs; + and − keep the fewest decimal places |
| Prefixes | k = 103, c = 10−2, m = 10−3, µ = 10−6, n = 10−9 |
What it looks like on the calculator
The calculator version is the same sheet in plain text with short lines, so it fits the screen. Square roots are written as sqrt( ), powers with ^ and Greek letters as words. On the calculator, search a word like “nitrate” or “Charles” to jump straight to it. The notes are stored in Archive, so a RAM clear won’t erase them.
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Which polyatomic ions are on the sheet?
26 of the common ones from a first-year chemistry list, from ammonium and nitrate to dichromate and thiosulfate, plus the -ate/-ite naming pattern. If your teacher’s list has others, add them in the editor before you check out.
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